Please use this identifier to cite or link to this item: http://elar.usfeu.ru/handle/123456789/8953
Title: The activity of element dioxides in liquid-phase oxidation of 2,3,5-trimethyl-1,4-hydroquinone
Authors: Shishmakov, A. B.
Kharchuk, V. G.
Kuznetsova, O. V.
Mikushina, Yu. V.
Koryakova, O. V.
Kovaleva, E. G.
Petrov, L. A.
Molochnikov, L. S.
Chupakhin, O. N.
Issue Date: 2003
Publisher: Pleiades Publishing
Citation: Shishmakov, A. B. The activity of element dioxides in liquid-phase oxidation of 2,3,5-trimethyl-1,4-hydroquinone / A. B. Shishmakov, V. G. Kharchuk, O. V. Kuznetsova [et al.] // Russian Journal of Physical Chemistry A. – 2003. – Vol. 77. – Iss. 4. – P. 548-552.
Abstract: The influence of silicon, tin, and titanium dioxide hydrogels on liquid-phase oxidative dehydrogenation of 2,3,5-trimethyl-1,4-hydroquinone in an aqueous-methanolic solution was studied by the method of initial reaction rates. The introduction of the gels inhibited the reaction, whereas Cu2+-containing gels accelerated it. The formation of Cu2+ compounds of various types in the gel phases was studied by EPR spectroscopy. The reactivities of these compounds were estimated.
Keywords: 2,3,5 TRIMETHYL 1,4 HYDROQUINONE
COPPER ION
HYDROQUINONE DERIVATIVE
METHANOL
OXIDE
SILICON
TIN
TITANIUM DIOXIDE
UNCLASSIFIED DRUG
AQUEOUS SOLUTION
ARTICLE
CHEMICAL ANALYSIS
CHEMICAL PARAMETERS
CHEMICAL REACTION
DEHYDROGENATION
ELECTRON SPIN RESONANCE
GEL
HYDROGEL
LIQUID
OXIDATION
URI: http://elar.usfeu.ru/handle/123456789/8953
SCOPUS: 2-s2.0-0038301215
WoS: WOS:000182382200007
RSCI: 13419377
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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