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dc.contributor.authorZakharova, G. S.en
dc.contributor.authorBuldakova, L. Yu.en
dc.contributor.authorVolkov, V. L.en
dc.contributor.authorMolochnikov, L. S.en
dc.contributor.authorKovaleva, E. G.en
dc.date.accessioned2019-09-20T15:19:15Z-
dc.date.available2019-09-20T15:19:15Z-
dc.date.issued2006-
dc.identifier.citationZakharova, G. S. Electrochemical properties and state of paramagnetic centers in copper-modified complex vanadium and titanium oxides / G. S. Zakharova, L. Yu. Buldakova, V. L. Volkov [et al.] // Russian Journal of Electrochemistry. – 2006. – Vol. 42. – Iss. 1. – P. 53-58.en
dc.identifier.issn1023-1935-
dc.identifier.urihttps://elar.usfeu.ru/handle/123456789/8904-
dc.description.abstractComplex vanadium and titanium oxides modified by copper ions are studied by the electrochemical and ESR methods. Oxides Cu x V2-y Ti y O5-δ•nH2O (0<y<1.33) have a layered structure and oxides Cu x Ti1-y V y O5+δ•nH2O (0<y<0.25), an anatase structure. The intercalation of cations Cu2+ into the hydrates leads to oxidation of V4+. According to ESR data, V 4+ exists in the oxides in the form of VO2+ and an octahedral surround of oxygen (V4+-O6), respectively. The electroreduction of ions of d-elements and chemisorbed oxygen in the oxides is analyzed. The intercalation of cations Cu2+ alters the content of V4+ and the chemisorption ability of the oxides. Possible reasons for this phenomenon are discussed. © MAIK "Nauka/Interperiodica" 2006.en
dc.description.sponsorshipThis work was supported by the Education Ministry of the Russian Federation within scientific–technical program “Scientific research of Higher School in high-priority fields of science and technology,” project no. 203.06.06.032.en
dc.language.isoenen
dc.publisherPleiades Publishingen
dc.rightsinfo:eu-repo/semantics/restrictedAccessen
dc.sourceRussian Journal of Electrochemistryen
dc.subjectCOPPER(II)en
dc.subjectESR SPECTROSCOPYen
dc.subjectINTERCALATIONen
dc.subjectVOLTAMETRYen
dc.subjectXEROGELS OF VANADIUM AND TITANIUM OXIDESen
dc.subjectCOPPER COMPOUNDSen
dc.subjectELECTROCHEMISTRYen
dc.subjectHYDRATESen
dc.subjectTITANIUM OXIDESen
dc.subjectANATASE STRUCTUREen
dc.subjectCHEMISORPTION ABILITYen
dc.subjectELECTROCHEMICAL PROPERTIESen
dc.subjectELECTROREDUCTIONen
dc.subjectPARAMAGNETIC RESONANCEen
dc.titleElectrochemical properties and state of paramagnetic centers in copper-modified complex vanadium and titanium oxidesen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
local.description.firstpage53-
local.description.lastpage58-
local.issue1-
local.volume42-
local.identifier.wosWOS:000235577900009-
local.identifier.doi10.1134/S1023193506010095-
local.affiliationInstitute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russian Federationen
local.affiliationUral State University of Forestry Engineering, Yekaterinburg, Russian Federationen
local.contributor.employeeZakharova, G.S., Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russian Federation
local.contributor.employeeBuldakova, L.Yu., Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russian Federation
local.contributor.employeeVolkov, V.L., Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russian Federation
local.contributor.employeeMolochnikov, L.S., Ural State University of Forestry Engineering, Yekaterinburg, Russian Federation
local.contributor.employeeKovaleva, E.G., Ural State University of Forestry Engineering, Yekaterinburg, Russian Federation
local.identifier.rsi13505838-
local.identifier.eid2-s2.0-33644682579-
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