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https://elar.usfeu.ru/handle/123456789/8816| Title: | Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds |
| Authors: | Pavlova, I. S. Pervova, I. G. Belov, G. P. Khasbiullin, I. I. Slepukhin, P. A. |
| Issue Date: | 2013 |
| Publisher: | Pleiades Publishing |
| Citation: | Pavlova, I. S. Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds / I. S. Pavlova, I. G. Pervova, G. P. Belov [et al.] // Petroleum Chemistry. – 2013. – Vol. 53. – Iss. 2. – P. 127-133. |
| Abstract: | A number of iron(II) complexes have been synthesized on the basis of benzothiazolylformazans, and their structure and composition have been characterized by elemental analysis, mass spectrometry, and X-ray analysis. The catalytic behavior of Fe(II) formazanates in the reaction of ethylene oligomerization in the presence of various organoaluminum compounds has been studied. Methylaluminoxane facilitates the formation of α-olefins (butene-1, hexene-1) and the byproducts hexene isomers; ethylaluminum dichloride (AlC2H5Cl2) increases the selectivity for alkyltoluenes. © 2013 Pleiades Publishing, Ltd. |
| Keywords: | ETHYLENE IRON FORMAZANATES OLIGOMERIZATION ORGANOALUMINUM COMPOUNDS CATALYTIC BEHAVIOR ETHYLENE OLIGOMERIZATIONS HEXENE ISOMERS IRON COMPLEX METHYLALUMINOXANE ORGANOALUMINUM COMPOUNDS ALUMINUM COMPOUNDS BYPRODUCTS ETHYLENE ISOMERS MASS SPECTROMETRY OLIGOMERIZATION OLIGOMERS SYNTHESIS (CHEMICAL) IRON COMPOUNDS |
| URI: | https://elar.usfeu.ru/handle/123456789/8816 |
| DOI: | 10.1134/S0965544113020072 |
| SCOPUS: | 2-s2.0-84880471661 |
| WoS: | WOS:000316202200010 |
| RSCI: | 20443965 |
| Appears in Collections: | Научные публикации, проиндексированные в SCOPUS и WoS CC |
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| 2-s2.0-84880471661.pdf | 257,03 kB | Adobe PDF | View/Open Request a copy |
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